Hmm... in that case it might be easier to deal with this in a calculated column. Not sure.
I can imagine a measure like... uh... hrm...
=IF(MIN(MyTable[Date]) = CALCULATE(MIN(MyTable[Date]) ALL(Calendar)), 1, 0)
If the smallest date in THIS pivot cell, for this job is equal to the smallest date in the WHOLE calendar... return 1, else 0. Untested theory.
For a calc column, you could try finding the smallest date associated with each job #.
=CALCULATE(MIN(MyTable[Date]), FILTER(MyTable, MyTable[Job#] = EARLIER(MyTable[Job#])))
Then, maybe use that in a unique count measure?
=CALCULATE(DISTINCTCOUNT(MyTable[Job#]), FILTER(MyTable, MyTable[Date] = MyTable[FirstDate]))
All untested -- apologies a bit too much client work right now to give this proper attention.