I have never used this function before, but a quick test of the function looks like it deliers a slope value. You have only specified one column (A1 to A20)so I think the function assumes all you x values are the same (i.e. same distance apart on a graph). Polynomials require x and y values. You must have an array.
For a polynomial I would try
Add x values that correlate to column A into column B. Then square your x values in c1 to c20, cubing you x values in d1 to d20...etc to the number of coeficients you desire. Then select col. A for Y values, and all the column X columns for the xrange.
Don't know how the trend funtion will handle that, but using the regression option in the data analysis tools will work great. If you select the entire X array as the X range, the regression analysis tool will spit out all the coefficients for your polynomial.
Hope this helps