I dont understand the phrase "86 players in the masters field and 86 in the deal".
Are these the same 86 players or 2 x 86 ?
Random list, no duplicates
A1:A86 List of names
B1:B86 =RAND()
C1:C86 =INDEX(A$1:A$86,MATCH(SMALL(B$1:B$86,ROW()),B$1:B$86,0))
This will produce a list of 86 names in column C in random order without duplicates.
From theat list make your selections.