I assume that by 45 degree line, you mean a line with a slope of 1 that passes through 0, 0?
If so, you can make another data series and plot that.
1, 1
2, 2
3, 3
That will give you a picture of that line.
The other part of the problem is not as direct. Basically, you will have to set equation of one line, equal to the other to find the X intersect.
So, if you have the following
f(x) = x (this is your reference line)
and
g(x) = mx + b
Then your x intersect would be
x = b/(1-m)
Translated to an Excel Formula, that would be something like:
=INTERCEPT(F19:F23,E19:E23)/(1-SLOPE(F19:F23,E19:E23))
Where Column F has your Y values, and column E has your X values.
So to get your Y value for the intersect, you would use something like
=SLOPE(F19:F23,E19:E23)*INTERCEPT(F19:F23,E19:E23)/(1-SLOPE(F19:F23,E19:E23))+INTERCEPT(F19:F23,E19:E23)
.....
I think....